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Beilstein J. Org. Chem. 2012, 8, 675–682, doi:10.3762/bjoc.8.75
Graphical Abstract
Scheme 1: Different strategies to access C-glycosides starting from 1-substituted glycals.
Scheme 2: Sonogashira–Hagihara reaction of 1-iodo-2-chloroglucal 12 with phenylacetylene (8a) to afford 13.